Serveur d'exploration sur le nickel au Maghreb

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Separation and identification of petroporphyrins extracted from the oil shales of Tarfaya: geochemical study

Identifieur interne : 000300 ( France/Analysis ); précédent : 000299; suivant : 000301

Separation and identification of petroporphyrins extracted from the oil shales of Tarfaya: geochemical study

Auteurs : A. Doukkali [Maroc] ; A. Saoiabi [Maroc] ; A. Zrineh [Maroc] ; M. Hamad [Maroc] ; M. Ferhat [Maroc] ; J. M. Barbe [France] ; R. Guilard [France]

Source :

RBID : Pascal:02-0233508

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English descriptors

Abstract

Vanadyl and nickel porphyrins were isolated from the oil shales of Tarfaya (Morocco) by extraction followed by column chromatography. The ratios and characteristics of these porphyrin complexes were essentially obtained on the basis of UV-visible and mass spectrometry data. Geochemical information could be drawn from these data. The nature and the contents of the metals coordinated and non-coordinated to porphyrin systems were also determined in this study.


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Pascal:02-0233508

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<term>Oil shale</term>
<term>Solvent extraction</term>
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<term>Schiste bitumineux</term>
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<div type="abstract" xml:lang="en">Vanadyl and nickel porphyrins were isolated from the oil shales of Tarfaya (Morocco) by extraction followed by column chromatography. The ratios and characteristics of these porphyrin complexes were essentially obtained on the basis of UV-visible and mass spectrometry data. Geochemical information could be drawn from these data. The nature and the contents of the metals coordinated and non-coordinated to porphyrin systems were also determined in this study.</div>
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